Electroless nickel plating is a nickel - phosphorus alloy which can be applied to metallic surface and also to semi-conducting materials to provide coatings which are of uniform thickness and have excellent chemical and physical properties.
The term 'Electroless' is applied to these coatings as they are deposited without the use of an electric current as in conventional electroplating. This plating has the ability to cover complex geometry & internal as well as external surface, holes, recesses and threaded parts.
The main features of this coating that distinguish them uniformity of thickness distribution, hardness & low level of stress. IT is a chemical reduction process which depends upon the catalytic reduction process of nickel ions in an aqueous solution (containing a chemical reducing agent) and the subsequent deposition of nickel metal without the use of electrical energy.
Due to its exceptional corrosion resistance and high hardness, the process finds wide application on items such as valves, pump parts etc., to enhance the life of components exposed to severe conditions of service, particularly in the oil field and marine sector. With correct pretreatment sequence and accurate process control, good adhesion and excellent service performance can be obtained from EN deposited on a multitude of metallic and non-metallic substractes.
The versatility of electroless nickel plating is demonstrated by the wide range of coatings possible. The following are important types of coatings industrially available (reference)
Medium Phosphorous (Bright High Speed)
This is a workhorse electroless nickel. It has proven itself over the years. Steel parts plated with Medium Phosphorous electroless nickel Plating will in many cases perform like stainless steel. Electroless nickel will not build up on edges or ends, and it plates inside and out giving uniform total coverage. With heat treatment, medium phosphorous electroless nickel can be hardened from 45 Rockwell C to as high as 68 Rockwell C.
High Phosphorous
This finish provides maximum corrosion resistance. High Phosphorous electroless nickel Plating is standard in industries that require resistance to strongly acidic corrosive environments like oil drilling and coal mining. High Phosphorous electroless nickel has a low degree of solderability. It will remain solderable for only a brief period of time after plating. This makes it a desirable finish for electronics parts such as connector housings and semiconductor packaging.